Rarity is the fashion designer from My Little Pony, Friendship is Magic.
This episode was from the season 1 finale, called "The Best Night Ever"
Rarity makes this expression while Pinkie Pie is singing the Pony Pokey, because Blueblood refuses to open the door for her and then turns his head stubbornly.
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:icon madrarityplz: with no spaces.
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